There may have been five goals scored in this match but there was only two goalscorers with Lionel Messi scoring a hat-trick and also new recruit Helder Postiga netting himself a brace.
The Catalans are now sitting on top of the La Liga with three other teams equal on points with goal difference the separator.
Valencia meanwhile have had mixed results with one win from their first three games but will face a tricky encounter when they travel to face Betis.
Half Time Score: Valencia 2 - 3 Barcelona
Full Time Score: Valencia 2 - 3 BarcelonaGoals and key events:
11' Messi
39' Messi
41' Messi
45' Postiga
45+3' Postiga
At the completion of the match you will be able to view the highlights in the Highlights room link below or you can view the highlights if below aswell.